WebThe major challenges are the inherent poor photoreactivity of enzymes and the difficulty in achieving stereochemical control of the remote prochiral radical intermediate 7. Here we … WebOct 8, 2024 · The photoenzymatic decarboxylation of fatty acids to alkanes is proposed as an alternative approach for the synthesis of biodiesel. By using a recently discovered photodecarboxylase from Chlorella variabilis NC64A (CvFAP) we demonstrate the irreversible preparation of alkanes from fatty acids and triglycerides. Several fatty acids …
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WebAug 28, 2024 · Flavin-dependent “ene”-reductases can generate stabilized alkyl radicals when irradiated with visible light; however, they are not known to form unstabilized radicals. Here, we report an enantioselective radical cyclization using alkyl iodides as precursors to unstabilized nucleophilic radicals. Evidence suggests this species is accessed by … WebAug 28, 2024 · Flavin-dependent “ene”-reductases can generate stabilized alkyl radicals when irradiated with visible light; however, they are not known to form unstabilized … hyper-v does not have permission to open
Photoenzymatic Catalysis in a New Light: Gluconobacter “Ene”-Reducta…
WebSep 16, 2024 · DOI: 10.33774/chemrxiv-2024-955hf Corpus ID: 239046603; Photoenzymatic Synthesis of α-Tertiary Amines by Engineered Flavin-Dependent "Ene"-Reductases. @article{Gao2024PhotoenzymaticSO, title={Photoenzymatic Synthesis of $\alpha$-Tertiary Amines by Engineered Flavin-Dependent "Ene"-Reductases.}, author={Xin-Lian Gao and … WebDec 28, 2024 · Intermolecular C–C bond-forming reactions are underdeveloped transformations in the field of biocatalysis. Here we report a photoenzymatic intermolecular hydroalkylation of olefins catalyzed by flavin-dependent ‘ene’-reductases. Radical initiation occurs via photoexcitation of a rare high-order enzyme-templated charge-transfer … WebNov 1, 2024 · Herein, we described photoenzymatic dynamic kinetic resolution (DKR) of amines under mild conditions. The racemization of amines via a photoredox-mediated … hyper-v download free windows 10